Phase and microstructure evolution of Sc2O3–CeO2 –ZrO2ceramics in Na2SO4 + V2O5 molten salts

In this study, the destabilization resistance of Sc₂O₃ and CeO₂ co-stabilized ZrO₂ (SCZ) ceramics was tested in Na₂SO₄ + V₂O₅ molten salts at 750°C–1100 °C. The phase structure and microstructure evolution of the samples during the hot corrosion testing were analyzed with X-ray diffraction (XRD), Raman spectra, scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), and X-ray photoelectron spectroscopy (XPS). Results showed that the destabilization of SCZ ceramics at 750 °C was the result of the chemical reaction with V₂O₅ to produce m-ZrO₂ and CeVO₄, and little ScVO₄ was detected in the Sc₂O₃-rich SCZ ceramics. The primary corrosion products at 900 °C and 1100 °C were CeO₂ and m-ZrO₂ due to the mineralization effect. The Sc₂O₃-rich SCZ ceramics exhibited excellent degradation resistance and phase stability owing to the enhanced bond strength and the decreased size misfit between Zr⁴⁺ and Sc³⁺. The destabilization mechanism of SCZ ceramic under hot corrosion was also discussed.     

Facile Fabrication of Luminescent Eu(III) Functionalized HOF Hydrogel Film with Multifunctionailities: Quinolones Fluorescent Sensor and Anticounterfeiting Platform

The luminescent hydrogen-bonded organic framework (HOF) based films have become one of the most remarkable materials for optical application, thus, developing facile synthesis methods and establishing multifunctional applications for HOF-based luminescent materials are essential. Herein, a dual-emitting Eu³⁺-functionalized HOF hydrogel film ( 1 ) is fabricated successfully. 1 emits a blue-green long afterglow when turning off the UV lamp, and the long afterglow lifetime gets to 1.99 s. 1 performs great selectivity, high sensitivity, and low detection limit toward ofloxacin and flumequine, and the sensing toward ofloxacin and flumequine is in accord with the chroma and ratio modes. The fluorescent response mechanisms of 1  toward ofloxacin and flumequine are investigated in depth, which are further utilized to build an anticounterfeiting platform with high-level security. The film-based anticounterfeiting platform can conduct information encryption on demand inline with different fluorescent responses and can also fetch specific information by controlling the long afterglow intensity and excited light. This study not only provides a representative case of the fabrication of dual-emitting Eu³⁺-functionalized HOF-based hydrogel film but also opens the possibility of HOF-based film as intelligent luminescent materials with multifunctionalities.     

Synergistic effect of bulk phase doping and layered-spinel structure formation on improving electrochemical performance of Li-Rich cathode material

In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g^?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li⁺ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material.     

西藏燕麦主要种植区灌溉定额空间分布及影响因素

燕麦为西藏自治区典型牧草之一,由于种植区地域辽阔,灌溉试验结果受限,西藏燕麦主要种植区的灌溉定额尚不明确。本文在西藏燕麦主要种植区内选取28个典型站点进行资料收集,遵循农业气候相似原则进行区域划分,基于水量平衡法揭示了西藏燕麦主要种植区灌溉定额的空间分布特征,并根据统计学原理分析了其影响因素。研究表明:燕麦主要种植区的灌溉定额呈由西藏中部至东部呈现先递增后递减的趋势,50%水文年下的燕麦灌溉定额在56~265 mm之间变化。降雨量是影响研究区内燕麦灌溉定额的主要因素(R²为0.515),ET₀次之(R²为0.152);其它气象因素中,日照时数对研究区燕麦灌溉定额影响较大(R²为0.462),且呈正相关关系;相对湿度对燕麦灌溉定额影响较小。西藏燕麦主要种植区的灌溉定额及其空间分布可为西藏自治区灌溉用水管理提供支撑。     

25%小偏置碰撞策略及测试评估研究

随着汽车事故的增加,且小重叠碰撞事故死亡率居高不下,小偏置碰撞试验逐渐成为焦点。基于IIHS公布的最新车辆碰撞试验结果,统计超过100余款不同类型的25%小偏置碰撞车辆,建立碰撞转角与碰撞区域的数学模型,将25%小偏置碰撞归结为三种不同的碰撞策略,分别是吸能策略、掠过策略和掠过与吸能策略;并进行试验验证,对三种策略的优缺点进行分析。结果表明,小偏置碰撞试验可运用合理的碰撞策略达到法规要求,对25%小偏置碰撞试验具有一定的参考价值。     

基于STEAM的机器人竞技平台研发

基于创客和STEAM教育理念研制一种适用于中小学生的机器人竞技平台.通过机器人模块化设计分析和图形编程,达到了满足学生动手改装机器人需求的目的.该平台可以实现多机器人竞技赛和对抗赛,能够实时显示比赛图像、机器人位置信息和运行参数,并提供自动控制和遥控两种控制模式,自动完成实时计分与比赛结果统计,为机器人竞技比赛和中小学生STEAM教育提供了可靠设备.     

半球环形全景成像紫外光学系统设计

阐述了一种基于半球环形全景成像的紫外光学系统,从大视场的需求角度出发,设计了半球环形的全景成像光学系统,该系统可以实现对180°(H)×40°(V)空域实现成像覆盖的需求,系统适用于紫外成像,由于紫外波段系统材料较少,为减小系统像差,在第一片镜片采用了镀膜折返式方式进行设计,该设计不但实现了扩大系统视场接收范围的能力,还具备了镜片数量少的特点.所设计的系统体积小,覆盖面积广,成像质量高,有效的实现了环形大视场范围紫外图像获取.     

Modulation of electrical transport in calcium cobaltite ceramics and thick films through microstructure control and doping

Ca₃Co₄O₉ is a promising p-type thermoelectric oxide material having intrinsically low thermal conductivity. With low cost and opportunities for automatic large scale production, thick film technologies offer considerable potential for a new generation of micro-sized thermoelectric coolers or generators. Here, based on the chemical composition optimized by traditional solid state reaction for bulk samples, we present a viable approach to modulating the electrical transport properties of screen-printed calcium cobaltite thick films through control of the microstructural evolution by optimized heat-treatment. XRD and TEM analysis confirmed the formation of high-quality calcium cobaltite grains. By creating 2.0 at% cobalt deficiency in Ca_2.7Bi_0.3Co₄O_9+δ, the pressureless sintered ceramics reached the highest power factor of 98.0 μWm^?1 K^-2 at 823 K, through enhancement of electrical conductivity by reduction of poorly conducting secondary phases. Subsequently, textured thick films of Ca_2.7Bi_0.3Co_3.92O_9+δ were efficiently tailored by controlling the sintering temperature and holding time. Optimized Ca_2.7Bi_0.3Co_3.92O_9+δ thick films sintered at 1203 K for 8 h exhibited the maximum power factor of 55.5 μWm^?1 K^-2 at 673 K through microstructure control.     

人体步态差异性的参数化辨识方法及应用

通过对下肢3 个关节步态曲线建立具有共性控制点的数学模型,提出了以个体的局部形状参数作为区别同一关节中不同曲线的方法.实验采用Perception Neuron 动作捕捉系统,对正常组10 名健康男性青年,验证组2 名健康和3 名处于不同康复期的右腿踝关节损伤男性青年在正常步速下的步态数据进行实验测量以获得髋关节、膝关节和踝关节的上下位移轨迹曲线,并计算得出正常组步态曲线的局部形状参数作为判别步态正常与否的参考调整范围.经分析,验证组中健康被试者的局部形状参数大多属于该范围,而恢复较差的病人参数大多超出该范围,表明该参数化方法可有效辨别步态曲线差异,此外还可对康复评价的方法提供依据.     

强粘性地层的旋挖钻孔灌注桩充盈系数控制研究

旋挖钻孔因施工效率高、适应地层能力强的特点,已在各类工程的桩基施工中得到广泛应用.结合强粘性含卵砾石地层的工程案例,通过分析其施工难点,研究旋挖钻头选型与改进及泥浆性能调配.应用结果表明,改进的旋挖钻头配合优化的泥浆性能可有效防止钻头泥包并保持孔壁稳定,实现高效快速钻进,显著降低混凝土充盈系数;节省材料成本和劳务成本,提高工程效益.